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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Prato reaction ： ウィキペディア英語版 Prato reaction The Prato reaction is a particular example of the well-known 1,3-dipolar cycloaddition of azomethine ylides to olefins. In fullerene chemistry this reaction refers to the functionalization of fullerenes and nanotubes. The amino acid sarcosine reacts with paraformaldehyde when heated at reflux in toluene to an ylide which reacts with a double bond in a 6,6 ring position in a fullerene via a 1,3-dipolar cycloaddition to yield a N-methylpyrrolidine derivative or pyrrolidinofullerene or pyrrolidino3,4:1,2 ()fullerene in 82% yield based on C60 conversion. ==Applications== In one application a liquid fullerene is obtained when the pyrrolidone substituent is a 2,4,6-tris(alkyloxy)phenyl group although a small amount of solvent is still possibly present. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Prato reaction」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.